Because enzymes, which are proteins, don't form by chance. They form by specific chemical reactions. By the way, Hoyle was also wrong about the expansion of the universe.
In any case, in living systems, proteins are formed by the action of mRNA and tRNA reading out and converting the code in a DNA molecule. That coding is the result of selection in the evolutionary process.
If you cannot understand how probability actually enters into it, from the starting point, if there are a very large number of possible outcomes resulting from a process, say 100 trillion, that means the possibility of any particular outcome is 1 in 100 trillion. It does not mean there will be no outcome.
You cannot take an after-the-fact result and say that the result was impossible because of the odds. Just as you cannot say that Big Jim Conners could not have won that poker game last night because the hand he was supposed to have won with had a 1 in 250,000,000 chance of being dealt.
The same is true concerning particular proteins, genes, or what have you. There are a virtually infinite number of possible proteins, for example, some of which would be considerably better at performing a particular function than the one performing that function today, but which never came up in the poker game of life. All that is actually required is that a particular protein that did come up is able to adequately do the job it needs to do, even if it is not able to do the job as well as another protein could have, but which never came up in the shuffle. In the same way, you might not be dealt a straight flush in a poker game, but you could still win with a pair of eights if your opponent was dealt only a pair of threes.
As for the odds of life beginning, all that is required is a self-replicating molecule. Once we have that, the first primitive cell is not that far away biologically speaking.
This site shows what can happen.
http://www.wired.com/wiredscience/2009/05/ribonucleotides
Here is a quote from that site:
"[T]hough researchers have been able to show how RNA’s component molecules, called ribonucleotides, could assemble into RNA, their many attempts to synthesize these ribonucleotides have failed. No matter how they combined the ingredients — a sugar, a phosphate, and one of four different nitrogenous molecules, or nucleobases — ribonucleotides just wouldn’t form."
But now the ribonucleotides have been spontaneously formed in the lab--it was just a matter of finding the correct precursor chemicals. And this is a quote from the scientist involved.
“Ribonucleotides are simply an expression of the fundamental principles of organic chemistry,” said Sutherland. “They’re doing it unwittingly. The instructions for them to do it are inherent in the structure of the precursor materials. And if they can self-assemble so easily, perhaps they shouldn’t be viewed as complicated.”
Given what can take place in a lab, what can take place in the whole earth and over millions of years is not hard to conceive. Here are some sites that present some of the latest findings.
http://www.sciencedaily.com/releases/2002/12/021204080856.htm
http://www.gla.ac.uk/projects/originoflife/html/2001/pdf_files/Martin_&_Russell.pdf
http://www.pubmedcentral.nih.gov/picrender.fcgi?artid=1693098&blobtype=pdf
And where do you get your basis for determining the odds that a god exists?
Added:
And even if it could be proven that evolution did not occur, that does not mean that Yahwah, the primitive, abhorrent, psycho, tribal god that the ancient Israelites believed in, exists, any more than Zeus, Odin, Thor, or the god of any other ancient, superstitious people exists.